By Linus Pauling
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Extra info for College Chemistry : An Introductory Textbook of General Chemistry
We will assume they are first order for the drawn spectrum. 5A. 5E. 5F. 5G. 5H. 5I. 5K. 5L. 5Q. 5U. 6 23 O 1 3 2 4 4-Heptanone A Pople Notation -- A3M2X2; 2 and 3 (and 5 and 6) are enantiotopic. 3 and 5, 2 and 6 are CSE. 1 OH 2 3 4 5 6 7 3-Heptanol B One spin system. 2,2’; 4,4’; 5,5’, and 6,6’ are diastereotopic. 3 2 5 1 4 Br 4-Bromotoluene C Two spin systems. Pople Notation -- AA’XX’. 2 and 2’ are CSE but not magnetically equivalent as are 3 and 3’. Br 3 5 4 2 2-Bromopentane 1 D One spin system.
2 (o) Spin Table or Calculation Coupled with Multiplet (n+1) Integration Appr. 00 * These are diastereotopic, and are coupled to diastereotopic protons; they would not be first order. We will assume they are first order for the drawn spectrum. 5A. 5E. 5F. 5G. 5H. 5I. 5K. 5L. 5Q. 5U. 6 23 O 1 3 2 4 4-Heptanone A Pople Notation -- A3M2X2; 2 and 3 (and 5 and 6) are enantiotopic. 3 and 5, 2 and 6 are CSE. 1 OH 2 3 4 5 6 7 3-Heptanol B One spin system. 2,2’; 4,4’; 5,5’, and 6,6’ are diastereotopic. 3 2 5 1 4 Br 4-Bromotoluene C Two spin systems.
5 and 6 are CSE. O 1 6 5 4 2 3 2-Cyclohexen-1-one W One spin system. 4, 5, and 6 are enantiotopic. 2 Note -- These are not close to observed values, but are the only answer from given tables.