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48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 28 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 3. EFFECTS OF INTERACTION, S I Z E , AND MORPHOLOGY Clarke, J. Κ. , and Ο Cinneide, A. D . , in " C a t a l y s i s " (J. W. ), Vol. 1, p . 685. , Amsterdam and American Elsevier, New York, 1973. Kahn, D. , Peterson, Ε. , and Somorjai, G. Α . , J. Catal. 34, 294 (1974). Boudart, M . , and Walters, A. B . , J. Am. Chem. Soc. 94, 6622 (1972). Somorjai, G. , Joyner, R. , and Lang, B . , Proc. Roy. Soc. 331, 335 (1972).
1973. 37. Ward, J. W . , U. S. Patent No. 3 , 7 8 1 , 199 (1974). 38. Ward, J. W . , U. S. Patent No. 3,897,327 (1975). 39. Kittrell, J. , U. S. Patent No. 3,639,271 (1972). 4 0 . Kittrell, J. , U . S. Patent N o . 3,558,471 (1971). 4 1 . Kittrell, J. , U. S. Patent No. 3,536,606 (1970). 42. Kittrell, J. , U. S. Patent No. 3,536,605. (1970). 4 3 . Kittrell, J. , U. S. Patent No. 3,535,227 (1970). 4 4 . Exell, S. F . , and Lux, B . , The Preparation and Structure of Ultrafine Carbide, Int. Conf.
In their methanation study  Dalla Betta et al. made 2 2 54 6. POISONING AND REGENERATION observations that point in this direction and have important practical conse quences. They find a strong effect of H S poisoning on the selectivity of a number of catalysts, including Ni and Rh on various supports, and speculate that the effect is due to the type of site interruption mentioned above.