By Rauter, Amelia Pilar; Lindhorst, Thisbe; Queneau, Yves
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Extra info for Carbohydrate Chemistry
A major contribution of Lubineau in water-promoted organic reactions was the pioneering work concerning the acceleration of aldolisation 12 | Carbohydr. , 2014, 40, 11–30 View Online Ph O O O O O OA ll O OBn 16 h MO 2C re face facial selectivity: 97/3 MO2C sugar 60 °C 99 % M = (-)-menthyl 12/04/2014 11:51:13. 1039/9781849739986-00011 Scheme 1 O OSiMe3 O OH Ph OH Ph + + PhCHO anti syn Scheme 2 O + + COMe COMe endo exo activation parameters (kJ . 9 Stereoselectivity was reversed in water aﬀording syn adducts as the major isomers.
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