By Kurt Faber
This, the 6th variation of the proven textbook on biocatalysis, feeds into undergraduate and graduate classes in smooth natural chemistry, in addition being a concise creation to the sphere. New fabric comprises color photographs and state of the art learn.
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Extra info for Biotransformations in Organic Chemistry: A Textbook
30: 81 Carrea G, Ottolina G, Riva S (1995) Trends Biotechnoi. 13: 63 Bell G, Halling PJ, Moore BD, Partridge J, Rees DG (1995) Trends Biotechnoi. 13: 468 Gutman AL, Shapira M (1995) Synthetic Applications of Enzymatic Reactions in Organic Solvents. In: Fiechter A (ed) Adv. Biochem. Eng. , vol 52, pp 87128, Springer, Berlin Heidelberg New York Menger FM (1993) Acc. Chern. Res. 26: 206 Only proteases are exceptions to this rule for obvious reasons. Sih CJ, Abushanab E, Jones JB (1977) Ann. Rep. Med.
E. of the remaining substrate. All the tricks to improve the optical purity of substrate and product of reversible enzymatic resolutions consist in shifting the reaction out of the equilibrium to obtain an irreversible type. The easiest way to achieve this is the use of an excess of cosubstrate: to obtain an equilibration constant of K > 10, about 20 molar equivalents of nucleophile versus substrate are considered to be sufficient to obtain a virtually irreversible type of reaction in most cases.
Int. Ed. Engi. , Chichester Buist PH, Dirnnik GP (1986) Tetrahedron Lett. 27: 1457 Schwab JM, Henderson BS (1990) Chern. Rev. 4 Enzyme Properties and Nomenclature 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 25 Fuganti C, Grasselli P (1988) Baker's Yeast Mediated Synthesis of Natural Products. In: Whitaker JR, Sonnet PE (eds) Biocatalysis in Agricultural Biotechnology, ACS Symposium Series, volume 389, pp 359-370 Toone EJ, Simon ES, Bednarski MD, Whitesides GM (1989) Tetrahedron 45: 5365 Kitazume T, Ikeya T, Murata K (1986) 1.